{"id":3993,"date":"2022-04-07T10:00:00","date_gmt":"2022-04-07T10:00:00","guid":{"rendered":"https:\/\/modernsciences.org\/staging\/4414\/?p=3993"},"modified":"2022-03-22T07:12:31","modified_gmt":"2022-03-22T07:12:31","slug":"novel-nanocrystal-gel-can-switch-between-gel-and-liquid-states","status":"publish","type":"post","link":"https:\/\/modernsciences.org\/staging\/4414\/novel-nanocrystal-gel-can-switch-between-gel-and-liquid-states\/","title":{"rendered":"Novel \u201cNanocrystal Gel\u201d Can Switch Between Gel and Liquid States"},"content":{"rendered":"\n<p>The concept of nanomaterials certainly isn\u2019t anything new\u2014innovations using these technologies are already <a href=\"https:\/\/modernsciences.org\/staging\/4414\/nanomaterials-may-soon-give-rise-to-better-surface-sealants-for-concrete\/\" target=\"_blank\" rel=\"noreferrer noopener\">slowly making their way towards everyday engineering innovations<\/a>\u2014but scientists from <a href=\"https:\/\/www.utexas.edu\/\" target=\"_blank\" rel=\"noreferrer noopener\">the University of Texas at Austin<\/a> (UTexas) just managed to make the future of telecommunications and energy just made things a lot more interesting by making a new type of \u201c<em>nanocrystal gel<\/em>\u201d that can be tuned to change between two different states.<\/p>\n\n\n\n<p>This gel, composed of tiny <em>tin-doped indium oxide<\/em> (ITO) nanocrystals some 10,000 times smaller than the width of a human hair, which were functionalized with terminated ligands and dispersed in <em>N,N-dimethylformamide <\/em>(DMF) solvent which contained excess cobalt (Co<sup>2+<\/sup>) and chloride (Cl<sup>&#8211;<\/sup>) ions. This particular mixture of compounds enabled the overall system to be coaxed into switching between a liquid or a \u201cgelled\u201d state by changing its temperature.<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img  decoding=\"async\"  src=\"data:image\/png;base64,iVBORw0KGgoAAAANSUhEUgAAAAEAAAABAQMAAAAl21bKAAAAA1BMVEUAAP+KeNJXAAAAAXRSTlMAQObYZgAAAAlwSFlzAAAOxAAADsQBlSsOGwAAAApJREFUCNdjYAAAAAIAAeIhvDMAAAAASUVORK5CYII=\"  alt=\"\"  class=\" pk-lazyload\"  data-pk-sizes=\"auto\"  data-pk-src=\"https:\/\/lh5.googleusercontent.com\/iMUwvdIOxHxQau395oS4dT3bkgSycjuem85j_DoK4znsxu-RIuqJEarfR4aKZCdSCKxmMKqfH_1X6a4a937s1CNZ5Uvbve_q_FUX-wRQl-HUoWWuvfdEYVYuigl4hsVOTJclgK5y\" ><figcaption>The gel, with nanocrystals dispersed within its matrix, would gel up and reverse its gelling in response to changes in temperature. (Kang et al, 2022)<\/figcaption><\/figure><\/div>\n\n\n\n<p>Published in the journal <a href=\"https:\/\/www.science.org\/doi\/10.1126\/sciadv.abm7364\" target=\"_blank\" rel=\"noreferrer noopener\"><em>Science Advances<\/em><\/a>, the study was headed by UTexas graduate students Jiho Kang and Stephanie Valenzuela, and was worked on through the institution\u2019s <a href=\"https:\/\/mrsec.utexas.edu\/\" target=\"_blank\" rel=\"noreferrer noopener\">Center for Dynamics and Control of Materials<\/a>.<\/p>\n\n\n\n<p>&#8220;You could shift the apparent heat signature of an object by changing the infrared properties of its skin,&#8221; said UTexas <a href=\"https:\/\/che.utexas.edu\/\" target=\"_blank\" rel=\"noreferrer noopener\">McKetta Department of Chemical Engineering<\/a> professor and chair Delia Milliron. &#8220;It could also be useful for telecommunications which all use infrared wavelengths.&#8221;<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><img  decoding=\"async\"  src=\"data:image\/png;base64,iVBORw0KGgoAAAANSUhEUgAAAAEAAAABAQMAAAAl21bKAAAAA1BMVEUAAP+KeNJXAAAAAXRSTlMAQObYZgAAAAlwSFlzAAAOxAAADsQBlSsOGwAAAApJREFUCNdjYAAAAAIAAeIhvDMAAAAASUVORK5CYII=\"  alt=\"\"  class=\" pk-lazyload\"  data-pk-sizes=\"auto\"  data-pk-src=\"https:\/\/lh4.googleusercontent.com\/GpwDvzTjBPVPF1mJ-amt89wN3AHjD6O_C9GCR0nlLsuA1Jm0nyD0LaTULQzJms0u3rg5q4aWr8NSw8TzAXgg0v7CQ8YcK7LahWBtmHIxSuAuZEakUKGdyrvoevR3c_ZDrP0aYLcw\" ><figcaption>The nanocrystal gel\u2019s ability to absorb infrared radiation may give the material novel applications in the field of defense technologies. (jcutrer.com, 2017)<\/figcaption><\/figure><\/div>\n\n\n\n<p>The operating principle governing the novel material relied on the fact that the nanocrystal gel absorbed different frequencies of light depending on its state; this, according to <a href=\"https:\/\/phys.org\/news\/2022-02-versatile-nanocrystal-gel-enable-advances.html\" target=\"_blank\" rel=\"noreferrer noopener\">UTexas via Phys.org<\/a>, meant that the material may present new opportunities in the field of telecommunications and defense in terms of thermal camouflage.<\/p>\n\n\n\n<p>Additionally, the material may be incorporated into new sensors that change either state or color in the presence of specific targets, which can then be used in the detection of dangerous substances and in the targeted delivery of treatment to cancer cells.<\/p>\n\n\n\n<h2 id=\"references\" class=\"wp-block-heading\">References<\/h2>\n\n\n\n<ul class=\"wp-block-list\"><li>Irving, M. (2022, February 21). <em>State-switching nanocrystal gel makes for cooling or thermal camouflage<\/em>. New Atlas. <a href=\"https:\/\/newatlas.com\/materials\/nanocrystal-gel-switches-states-active-camouflage\/\" target=\"_blank\" rel=\"noopener\">https:\/\/newatlas.com\/materials\/nanocrystal-gel-switches-states-active-camouflage\/<\/a><\/li><li>Kang, J., Valenzuela, S. A., Lin, E. Y., Dominguez, M. N., Sherman, Z. M., Truskett, T. M., Anslyn, E. V., &amp; Milliron, D. J. (2022). Colorimetric quantification of linking in thermoreversible nanocrystal gel assemblies. <em>Science Advances<\/em>, <em>8<\/em>(7), eabm7364. <a href=\"https:\/\/doi.org\/10.1126\/sciadv.abm7364\" target=\"_blank\" rel=\"noopener\">https:\/\/doi.org\/10.1126\/sciadv.abm7364<\/a><\/li><li>University of Texas at Austin. (2022, February 18). <em>Versatile \u2018nanocrystal gel\u2019 could enable advances in energy, defense and telecommunications<\/em>. Phys.Org. <a href=\"https:\/\/phys.org\/news\/2022-02-versatile-nanocrystal-gel-enable-advances.html\" target=\"_blank\" rel=\"noopener\">https:\/\/phys.org\/news\/2022-02-versatile-nanocrystal-gel-enable-advances.html<\/a><\/li><\/ul>\n","protected":false},"excerpt":{"rendered":"The concept of nanomaterials certainly isn\u2019t anything new\u2014innovations using these technologies are already slowly making their way towards&hellip;\n","protected":false},"author":4,"featured_media":3994,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"nf_dc_page":"","fifu_image_url":"","fifu_image_alt":"","footnotes":""},"categories":[15],"tags":[295],"class_list":{"0":"post-3993","1":"post","2":"type-post","3":"status-publish","4":"format-standard","5":"has-post-thumbnail","7":"category-engineering","8":"tag-nanotechnology","9":"cs-entry","10":"cs-video-wrap"},"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/posts\/3993","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/users\/4"}],"replies":[{"embeddable":true,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/comments?post=3993"}],"version-history":[{"count":1,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/posts\/3993\/revisions"}],"predecessor-version":[{"id":3995,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/posts\/3993\/revisions\/3995"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/media\/3994"}],"wp:attachment":[{"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/media?parent=3993"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/categories?post=3993"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/tags?post=3993"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}