{"id":11349,"date":"2024-03-05T22:00:00","date_gmt":"2024-03-05T22:00:00","guid":{"rendered":"https:\/\/modernsciences.org\/staging\/4414\/?p=11349"},"modified":"2024-02-22T10:35:53","modified_gmt":"2024-02-22T10:35:53","slug":"3d-printing-promises-more-efficient-ways-to-make-custom-explosives-and-rocket-propellants","status":"publish","type":"post","link":"https:\/\/modernsciences.org\/staging\/4414\/3d-printing-promises-more-efficient-ways-to-make-custom-explosives-and-rocket-propellants\/","title":{"rendered":"3D printing promises more efficient ways to make custom explosives and rocket propellants"},"content":{"rendered":"\n  <figure>\n    <img  decoding=\"async\"  src=\"data:image\/png;base64,iVBORw0KGgoAAAANSUhEUgAAAAEAAAABAQMAAAAl21bKAAAAA1BMVEUAAP+KeNJXAAAAAXRSTlMAQObYZgAAAAlwSFlzAAAOxAAADsQBlSsOGwAAAApJREFUCNdjYAAAAAIAAeIhvDMAAAAASUVORK5CYII=\"  class=\" pk-lazyload\"  data-pk-sizes=\"auto\"  data-pk-src=\"https:\/\/images.theconversation.com\/files\/575456\/original\/file-20240213-26-q2ug1p.jpg?ixlib=rb-1.1.0&#038;rect=6%2C3%2C2111%2C1406&#038;q=45&#038;auto=format&#038;w=754&#038;fit=clip\" >\n      <figcaption>\n        3D printing can be used to build with all kinds of materials \u2013 even those that go \u2018boom.\u2019\n        <span class=\"attribution\"><a class=\"source\" href=\"https:\/\/www.gettyimages.com\/detail\/photo\/printer-printing-prototypes-royalty-free-image\/1459229120?phrase=3D+printer&#038;adppopup=true\" target=\"_blank\" rel=\"noopener\">kynny\/iStock via Getty Images<\/a><\/span>\n      <\/figcaption>\n  <\/figure>\n\n<span><a href=\"https:\/\/theconversation.com\/profiles\/monique-mcclain-1473163\" target=\"_blank\" rel=\"noopener\">Monique McClain<\/a>, <em><a href=\"https:\/\/theconversation.com\/institutions\/purdue-university-1827\" target=\"_blank\" rel=\"noopener\">Purdue University<\/a><\/em><\/span>\n\n<p>Imagine you\u2019re driving to work on a rainy day, when a distracted, reckless driver hits your car out of nowhere. With a \u201cboom,\u201d an air bag deploys faster than you can <a href=\"https:\/\/www.nhtsa.gov\/vehicle-safety\/air-bags\" target=\"_blank\" rel=\"noopener\">blink your eyes<\/a> to save your life. <\/p>\n\n<p>That air bag deployed rapidly thanks to an energetic material called <a href=\"https:\/\/cen.acs.org\/safety\/chemicals-make-airbags-inflate-changed\/100\/i41\" target=\"_blank\" rel=\"noopener\">sodium azide<\/a>, which generates nitrogen gas during a chemical reaction to inflate your airbag. But what\u2019s an energetic material? <\/p>\n\n<p>Energetic materials include <a href=\"https:\/\/www.osti.gov\/biblio\/1765628\" target=\"_blank\" rel=\"noopener\">propellants, pyrotechnics, fuels and explosives<\/a>, and they\u2019re used in all sorts of settings. <\/p>\n\n<p>Uses of energetic materials include <a href=\"https:\/\/www.explainthatstuff.com\/flares.html\" target=\"_blank\" rel=\"noopener\">flares<\/a>, <a href=\"https:\/\/www.compoundchem.com\/2014\/11\/20\/matches\/\" target=\"_blank\" rel=\"noopener\">matches<\/a>, <a href=\"https:\/\/www.youtube.com\/watch?v=a1Ef1PcPKjk\" target=\"_blank\" rel=\"noopener\">solid rocket boosters<\/a>, <a href=\"https:\/\/www.ict.fraunhofer.de\/en\/comp\/em\/treib.html\" target=\"_blank\" rel=\"noopener\">gun propellants<\/a>, hot <a href=\"https:\/\/www.twi-global.com\/technical-knowledge\/faqs\/what-is-cad-welding\" target=\"_blank\" rel=\"noopener\">thermite welding<\/a> used to fuse materials together, <a href=\"https:\/\/theconversation.com\/how-do-fireworks-work-a-pyrotechnics-chemist-explains-the-science-behind-the-brilliant-colors-and-sounds-173576\" target=\"_blank\" rel=\"noopener\">fireworks<\/a> and the <a href=\"https:\/\/www.gq.com\/video\/watch\/the-breakdown-gq-the-breakdown-explosions\" target=\"_blank\" rel=\"noopener\">explosive special effects<\/a> in your favorite action movie. <\/p>\n\n<figure class=\"align-left zoomable\">\n            <a href=\"https:\/\/images.theconversation.com\/files\/575457\/original\/file-20240213-30-hajfxf.jpg?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=1000&amp;fit=clip\" target=\"_blank\" rel=\"noopener\"><img  decoding=\"async\"  alt=\"A gold and white rocket, with flames coming out of its end, attached to a concrete scaffold.\"  src=\"data:image\/png;base64,iVBORw0KGgoAAAANSUhEUgAAAAEAAAABAQMAAAAl21bKAAAAA1BMVEUAAP+KeNJXAAAAAXRSTlMAQObYZgAAAAlwSFlzAAAOxAAADsQBlSsOGwAAAApJREFUCNdjYAAAAAIAAeIhvDMAAAAASUVORK5CYII=\"  class=\" pk-lazyload\"  data-pk-sizes=\"auto\"  data-ls-sizes=\"(min-width: 1466px) 754px, (max-width: 599px) 100vw, (min-width: 600px) 600px, 237px\"  data-pk-src=\"https:\/\/images.theconversation.com\/files\/575457\/original\/file-20240213-30-hajfxf.jpg?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=237&amp;fit=clip\"  data-pk-srcset=\"https:\/\/images.theconversation.com\/files\/575457\/original\/file-20240213-30-hajfxf.jpg?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=600&amp;h=750&amp;fit=crop&amp;dpr=1 600w, https:\/\/images.theconversation.com\/files\/575457\/original\/file-20240213-30-hajfxf.jpg?ixlib=rb-1.1.0&amp;q=30&amp;auto=format&amp;w=600&amp;h=750&amp;fit=crop&amp;dpr=2 1200w, https:\/\/images.theconversation.com\/files\/575457\/original\/file-20240213-30-hajfxf.jpg?ixlib=rb-1.1.0&amp;q=15&amp;auto=format&amp;w=600&amp;h=750&amp;fit=crop&amp;dpr=3 1800w, https:\/\/images.theconversation.com\/files\/575457\/original\/file-20240213-30-hajfxf.jpg?ixlib=rb-1.1.0&amp;q=45&amp;auto=format&amp;w=754&amp;h=943&amp;fit=crop&amp;dpr=1 754w, https:\/\/images.theconversation.com\/files\/575457\/original\/file-20240213-30-hajfxf.jpg?ixlib=rb-1.1.0&amp;q=30&amp;auto=format&amp;w=754&amp;h=943&amp;fit=crop&amp;dpr=2 1508w, https:\/\/images.theconversation.com\/files\/575457\/original\/file-20240213-30-hajfxf.jpg?ixlib=rb-1.1.0&amp;q=15&amp;auto=format&amp;w=754&amp;h=943&amp;fit=crop&amp;dpr=3 2262w\" ><\/a>\n            <figcaption>\n              <span class=\"caption\">Propellants help rockets blast off.<\/span>\n              <span class=\"attribution\"><a class=\"source\" href=\"https:\/\/en.wikipedia.org\/wiki\/Rocket_propellant#\/media\/File:Delta_IV_launch_2013-08-28.jpg\" target=\"_blank\" rel=\"noopener\">U.S. Air Force\/Joe Davila<\/a><\/span>\n            <\/figcaption>\n          <\/figure>\n\n<p>Energetic materials come in many shapes and sizes, but they\u2019re often in a solid form and release a lot of energy through <a href=\"https:\/\/www.nfpa.org\/news-blogs-and-articles\/blogs\/2023\/03\/27\/explosions-vs-deflagrations-vs-detonations\" target=\"_blank\" rel=\"noopener\">burning or exploding<\/a>, depending on their shape and the conditions they\u2019re operating in. <\/p>\n\n<p>I\u2019m a <a href=\"https:\/\/www.technologyreview.com\/innovator\/monique-mcclain\/\" target=\"_blank\" rel=\"noopener\">mechanical engineering professor<\/a> who studies <a href=\"https:\/\/scholar.google.com\/citations?user=whbrwS0AAAAJ&amp;hl=en\" target=\"_blank\" rel=\"noopener\">energetic materials<\/a>. Making energetic materials isn\u2019t easy, but developments in 3D printing could make customization easier, while allowing for more potential scientific applications. <\/p>\n\n<h2 id=\"the-role-of-geometry\">The role of geometry<\/h2>\n\n<p>How energetic materials are made affects the shapes that they come in and how they release energy over time. For example, solid rocket propellants are made <a href=\"https:\/\/www.youtube.com\/watch?v=E0bnPb1WIuc\" target=\"_blank\" rel=\"noopener\">similar to a cake<\/a> where a stand mixer stirs the \u201cbatter,\u201d which is mostly made of <a href=\"https:\/\/blogs.nasa.gov\/Rocketology\/tag\/ammonium-perchlorate\/\" target=\"_blank\" rel=\"noopener\">ammonium perchlorate, aluminum and a rubbery binder<\/a>, before it\u2019s poured into a pan. The \u201ccake\u201d solidifies in the pan while it bakes in the oven. <\/p>\n\n<p>Typically, rocket propellants have a cylindrical shape, but with a rod in the center. <a href=\"https:\/\/airandspace.si.edu\/collection-objects\/mandrel-rocket-manufacturing-solid-propellant-rocket-motor\/nasm_A20060526000\" target=\"_blank\" rel=\"noopener\">The rod<\/a> often has a specific <a href=\"https:\/\/www.nakka-rocketry.net\/th_grain.html\" target=\"_blank\" rel=\"noopener\">cross-sectional shape<\/a>, like a circle or a star. When the propellant solidifies, the rod is removed, leaving the core shape behind. <\/p>\n\n<p>The core shape affects how the propellant burns, which can affect the <a href=\"https:\/\/www.youtube.com\/watch?v=eVvIZ3f2tSU\" target=\"_blank\" rel=\"noopener\">thrust of the motor it\u2019s used in<\/a>. Just by changing the central shape of the propellant, you can make a motor accelerate, slow down or maintain its speed over time. <\/p>\n\n<p>But this traditional \u201ccake baking\u201d process limits the shapes that you can make. You must be able to remove the rod after the propellant solidifies, so if the rod\u2019s shape is too complex, you might break the propellant, which could make it burn erratically. <\/p>\n\n<p>Designing propellant shapes that make rockets go faster or fly farther is an active area of research, but engineers need new manufacturing methods to create these increasingly complex designs.<\/p>\n\n<h2 id=\"3d-printing-to-the-rescue\">3D printing to the rescue<\/h2>\n\n<p><a href=\"https:\/\/www.pcmag.com\/news\/3d-printing-what-you-need-to-know\" target=\"_blank\" rel=\"noopener\">3D printing<\/a> has revolutionized manufacturing in a variety of ways, and researchers like me are trying to understand how it can improve the performance of energetic materials. 3D printing uses a printer to stack up material <a href=\"https:\/\/www.youtube.com\/watch?v=Vx0Z6LplaMU\" target=\"_blank\" rel=\"noopener\">layer by layer<\/a> to build an object. <\/p>\n\n<p>3D printing allows you to make custom shapes, print multiple types of material in one part, and save money and material. <\/p>\n\n<figure>\n            <iframe loading=\"lazy\" width=\"440\" height=\"260\" src=\"https:\/\/www.youtube.com\/embed\/Vx0Z6LplaMU?wmode=transparent&amp;start=0\" frameborder=\"0\" allowfullscreen=\"\"><\/iframe>\n            <figcaption><span class=\"caption\">3D printing can be cost- and time-efficient.<\/span><\/figcaption>\n          <\/figure>\n\n<p>However, it is very challenging to 3D-print energetic materials for several reasons. Some <a href=\"https:\/\/ntrs.nasa.gov\/citations\/19720024117\" target=\"_blank\" rel=\"noopener\">energetic materials are very viscous<\/a>, which means it is very hard to squeeze that mixture out of a tube with a small nozzle. Imagine squeezing clay out of a small syringe \u2013 the material is too thick to easily move through the small hole. <\/p>\n\n<p>In addition, energetic materials can be dangerous if handled improperly. They can ignite if there is <a href=\"https:\/\/www.osti.gov\/servlets\/purl\/639810\" target=\"_blank\" rel=\"noopener\">too much heat<\/a> during the manufacturing process or during storage, or if they are exposed to a <a href=\"https:\/\/apps.dtic.mil\/sti\/tr\/pdf\/ADA322856.pdf\" target=\"_blank\" rel=\"noopener\">static electric shock<\/a>.<\/p>\n\n<h2 id=\"recent-progress\">Recent progress<\/h2>\n\n<p>Despite this, researchers have made a lot of progress in the <a href=\"https:\/\/doi.org\/10.1002\/prep.201900060\" target=\"_blank\" rel=\"noopener\">past decade<\/a> to overcome some of these challenges. For example, scientists have 3D-printed <a href=\"https:\/\/engineering.purdue.edu\/ME\/News\/inkjetprinted-thermite-combines-energetic-materials-and-additive-manufacturing\" target=\"_blank\" rel=\"noopener\">reactive inks onto electronics<\/a> to enable self-destruction if they fall into the wrong hands.<\/p>\n\n<figure>\n            <iframe loading=\"lazy\" width=\"440\" height=\"260\" src=\"https:\/\/www.youtube.com\/embed\/8QNQRhBstRg?wmode=transparent&amp;start=28\" frameborder=\"0\" allowfullscreen=\"\"><\/iframe>\n            <figcaption><span class=\"caption\">Scientists are studying how to print thin layers of thermite, a type of energetic material, onto surfaces.<\/span><\/figcaption>\n          <\/figure>\n\n<p>Theoretically, you could also 3D-print these inks strategically onto old satellites or the <a href=\"https:\/\/www.cnn.com\/2022\/02\/02\/world\/nasa-international-space-station-retire-iss-scn\/index.html\" target=\"_blank\" rel=\"noopener\">aging International Space Station<\/a> to break up these orbiting devices into <a href=\"https:\/\/arc.aiaa.org\/doi\/10.2514\/6.2024-2162\" target=\"_blank\" rel=\"noopener\">small enough debris<\/a> that burns up in the atmosphere before hitting the ground. <\/p>\n\n<p>Many researchers are looking into 3D-printing gun propellants. <a href=\"https:\/\/doi.org\/10.1002\/prep.201900176\" target=\"_blank\" rel=\"noopener\">Modifying the shape of gun propellants<\/a> could make bullets that can fly farther. <\/p>\n\n<p>Others have sought to use 3D printing to reduce the environmental impact of <a href=\"https:\/\/serdp-estcp.mil\/projects\/details\/a04a6382-e4d4-4e7e-b262-2febb6cae014\/wp19-1246-project-overview\" target=\"_blank\" rel=\"noopener\">gun propellants<\/a> and <a href=\"https:\/\/serdp-estcp.mil\/projects\/details\/7a5dc45b-a30b-485f-93ab-ec3731356b3c\/wp19-1300-project-overview\" target=\"_blank\" rel=\"noopener\">igniters that require harsh solvents<\/a> to manufacture. These solvents are unsafe, difficult to dispose of and can harm <a href=\"https:\/\/www.epd.gov.hk\/epd\/english\/environmentinhk\/air\/prob_solutions\/vocs_smog.html\" target=\"_blank\" rel=\"noopener\">the environment<\/a> and <a href=\"https:\/\/www.epa.gov\/indoor-air-quality-iaq\/volatile-organic-compounds-impact-indoor-air-quality\" target=\"_blank\" rel=\"noopener\">peoples\u2019 health<\/a>. <\/p>\n\n<p>I showed that it is possible to <a href=\"https:\/\/www.purdue.edu\/newsroom\/releases\/2018\/Q2\/now-you-can-3d-print-clay,-cookie-dough--or-solid-rocket-fuel.html\" target=\"_blank\" rel=\"noopener\">3D-print solid rocket propellants<\/a> that have similar properties to traditionally made propellants. With that research, we now have the opportunity to explore how <a href=\"https:\/\/doi.org\/10.2514\/1.B38282\" target=\"_blank\" rel=\"noopener\">propellants made of multiple materials burn<\/a>, which is new territory. <\/p>\n\n<figure>\n            <iframe loading=\"lazy\" width=\"440\" height=\"260\" src=\"https:\/\/www.youtube.com\/embed\/OIdLg4zeGso?wmode=transparent&amp;start=2\" frameborder=\"0\" allowfullscreen=\"\"><\/iframe>\n            <figcaption><span class=\"caption\">To 3D-print rocket propellants, you first need to figure out how to print very viscous materials.<\/span><\/figcaption>\n          <\/figure>\n\n<p>For example, instead of using a rod to made a cross-sectional shape in a propellant, you could <a href=\"https:\/\/doi.org\/10.2514\/1.B38128\" target=\"_blank\" rel=\"noopener\">3D-print a highly reactive material<\/a> that you could add to the center. Instead of having to remove that center material, you could burn it up so fast that it leaves a core shape behind. The reactive material would also add energy to the propellant. This would eliminate the need to use and remove a rod to make a central core.<\/p>\n\n<p>While much of this research is in its infancy, companies such as <a href=\"https:\/\/www.prnewswire.com\/news-releases\/x-bow-systems-launches-second-successful-bolt-rocket-301851088.html\" target=\"_blank\" rel=\"noopener\">X-Bow<\/a> have been 3D-printing propellants and conducting successful flight tests with these motors.<\/p>\n\n<p>Finally, several researchers have studied how <a href=\"https:\/\/www.machinedesign.com\/3d-printing-cad\/article\/21836373\/a-look-inside-the-explosive-3dprinting-industry\" target=\"_blank\" rel=\"noopener\">3D-printed explosives<\/a> detonate. When the explosives are printed into a grid-shaped lattice, they react differently when their pores are filled with air or water. This process produces a safer \u201c<a href=\"https:\/\/discover.lanl.gov\/news\/0317-high-explosives\/\" target=\"_blank\" rel=\"noopener\">switchable\u201d explosive<\/a> that does not react unless it is in a specific environment. <\/p>\n\n<p>3D-printing energetic materials is still a new field. Scientists have a long way to go before we completely understand how <a href=\"https:\/\/doi.org\/10.1002\/prep.202380231\" target=\"_blank\" rel=\"noopener\">3D printing affects their safety and performance<\/a>. But every day, scientists like me are finding new ways to use 3D-printed energetics to serve crucial, and sometimes lifesaving, purposes.<!-- Below is The Conversation's page counter tag. Please DO NOT REMOVE. --><img  loading=\"lazy\"  decoding=\"async\"  src=\"data:image\/png;base64,iVBORw0KGgoAAAANSUhEUgAAAAEAAAABAQMAAAAl21bKAAAAA1BMVEUAAP+KeNJXAAAAAXRSTlMAQObYZgAAAAlwSFlzAAAOxAAADsQBlSsOGwAAAApJREFUCNdjYAAAAAIAAeIhvDMAAAAASUVORK5CYII=\"  alt=\"The Conversation\"  width=\"1\"  height=\"1\"  style=\"border: none !important; box-shadow: none !important; margin: 0 !important; max-height: 1px !important; max-width: 1px !important; min-height: 1px !important; min-width: 1px !important; opacity: 0 !important; outline: none !important; padding: 0 !important\"  referrerpolicy=\"no-referrer-when-downgrade\"  class=\" pk-lazyload\"  data-pk-sizes=\"auto\"  data-pk-src=\"https:\/\/counter.theconversation.com\/content\/214126\/count.gif?distributor=republish-lightbox-basic\" ><!-- End of code. If you don't see any code above, please get new code from the Advanced tab after you click the republish button. The page counter does not collect any personal data. More info: https:\/\/theconversation.com\/republishing-guidelines --><\/p>\n\n<p><span><a href=\"https:\/\/theconversation.com\/profiles\/monique-mcclain-1473163\" target=\"_blank\" rel=\"noopener\">Monique McClain<\/a>, Assistant Professor of Mechanical Engineering, <em><a href=\"https:\/\/theconversation.com\/institutions\/purdue-university-1827\" target=\"_blank\" rel=\"noopener\">Purdue University<\/a><\/em><\/span><\/p>\n\n<p>This article is republished from <a href=\"https:\/\/theconversation.com\" target=\"_blank\" rel=\"noopener\">The Conversation<\/a> under a Creative Commons license. Read the <a href=\"https:\/\/theconversation.com\/3d-printing-promises-more-efficient-ways-to-make-custom-explosives-and-rocket-propellants-214126\" target=\"_blank\" rel=\"noopener\">original article<\/a>.<\/p>\n\n","protected":false},"excerpt":{"rendered":"3D printing can be used to build with all kinds of materials \u2013 even those that go \u2018boom.\u2019&hellip;\n","protected":false},"author":740,"featured_media":11369,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"nf_dc_page":"","fifu_image_url":"","fifu_image_alt":"","footnotes":""},"categories":[15,17,16],"tags":[402,772,313,646,474],"class_list":{"0":"post-11349","1":"post","2":"type-post","3":"status-publish","4":"format-standard","5":"has-post-thumbnail","7":"category-engineering","8":"category-math-and-the-sciences","9":"category-tech","10":"tag-3d-printing","11":"tag-chemical-engineering","12":"tag-chemistry","13":"tag-explosives","14":"tag-the-conversation","15":"cs-entry","16":"cs-video-wrap"},"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/posts\/11349","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/users\/740"}],"replies":[{"embeddable":true,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/comments?post=11349"}],"version-history":[{"count":1,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/posts\/11349\/revisions"}],"predecessor-version":[{"id":11350,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/posts\/11349\/revisions\/11350"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/media\/11369"}],"wp:attachment":[{"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/media?parent=11349"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/categories?post=11349"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/modernsciences.org\/staging\/4414\/wp-json\/wp\/v2\/tags?post=11349"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}